Aqua(4-fluorobenzoato-κO)bis(1,10-phenanthroline-κ2 N,N′)manganese(II) 4-fluorobenzoate trihydrate
نویسندگان
چکیده
In the title compound, [Mn(C(7)H(4)FO(2))(C(12)H(8)N(2))(2)(H(2)O)](C(7)H(4)FO(2))·3H(2)O, the Mn(II) atom is coordinated by four N atoms from two chelating 1,10-phenanthroline ligands and two O atoms from one monodentate 4-fluoro-benzoate ion and one water mol-ecule, forming a distorted octa-hedral geometry. In the crystal, the three components are assembled into a tape structure along the a axis by O-H⋯O and C-H⋯O hydrogen bonds. Between the tapes, a π-π inter-action with a centroid-centroid distance of 3.569 (3) Å and a weak C-H⋯F hydrogen bond are observed.
منابع مشابه
Aqua(3-fluorobenzoato-κO)(3-fluorobenzoato-κ2 O,O′)(1,10-phenanthroline-κ2 N,N′)cobalt(II)
In the title compound, [Co(C(7)H(4)FO(2))(2)(C(12)H(8)N(2))(H(2)O)], the Co(II) ion is coordinated by two O atoms from one 3-fluoro-benzoate (fb) ligand and one O atom from another fb ligand, two N atoms from the 1,10-phenanthroline ligand and a water mol-ecule in a distorted octa-hedral geometry. An intra-molecular O-H⋯O hydrogen bond occurs. Inter-molecular O-H⋯O hydrogen bonds link pairs of ...
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